Dynamics of uniaxial hard ellipsoids

Abstract

We study the dynamics of monodisperse hard ellipsoids via a new event-driven molecular dynamics algorithm as a function of volume fraction and aspect ratio X0. We evaluate the translational Dtrans and the rotational Drot diffusion coefficients and the associated isodiffusivity lines in the X0 plane. We observe a decoupling of the translational and rotational dynamics which generates an almost perpendicular crossing of the Dtrans and Drot isodiffusivity lines. While the self-intermediate scattering function exhibits stretched relaxation, i.e., glassy dynamics, only for large and X0≈1, the second order orientational correlator C2(t) shows stretching only for large and small X0 values. We discuss these findings in the context of a possible prenematic order driven glass transition. © 2007 The American Physical Society.

Publication
Physical Review Letters

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